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Which one of the following is an outer orbital complex and exhibits paramagnetic behaviour ?
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Outer orbital complex utilises (n -1) d-orbitals for bonding and exhibit paramagnetic behaviour, only if there present unpaired electrons.
(a) In:
So, this is an outer orbital complex as it involve 4d- orbitals for bonding, but having paramagnetic character.
(b) In
Thus, it is also an outer orbital complex as it involve 4d-orbitals for bonding but it is diamagnetic as all the electrons are paired.
(c) In
Because of the involvement of (n-1) d, i.e. 3d-orbital in hybridisation, it is an inner orbital complex. Its nature is paramagnetic because of the presence of three unpaired electrons.
(d) In
Because of the involvement of (n-1) d orbital in hybridisation, it is an inner orbital complex. As all the electrons are paired, it is a diamagnetic complex.
(a) In:
So, this is an outer orbital complex as it involve 4d- orbitals for bonding, but having paramagnetic character.
(b) In
Thus, it is also an outer orbital complex as it involve 4d-orbitals for bonding but it is diamagnetic as all the electrons are paired.
(c) In
Because of the involvement of (n-1) d, i.e. 3d-orbital in hybridisation, it is an inner orbital complex. Its nature is paramagnetic because of the presence of three unpaired electrons.
(d) In
Because of the involvement of (n-1) d orbital in hybridisation, it is an inner orbital complex. As all the electrons are paired, it is a diamagnetic complex.
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Question Text | Which one of the following is an outer orbital complex and exhibits paramagnetic behaviour ? |
Answer Type | Text solution:1 |
Upvotes | 150 |