The values of Kp1 and Kp2 for the reactions X⇔Y+Z ….(i) and A⇔2B …(ii) are in ratio of 9 : 1. If degree of dissociation of X and A be equal, then total presure at equilibrium (i) and (ii) are in the ratio.

Question

The values of Kp1​​ and Kp2​​ for the reactions  X⇔Y+Z ….(i)  and A⇔2B …(ii)  are in ratio of 9 : 1. If degree of dissociation of X and A be equal, then total presure at equilibrium (i) and (ii) are in the ratio.

Filo · Accepted Answer

In equation,Initial molesAt equil​X1(1−α)​⇔​Y0α​+​Z0α​  where, α = degree of dissociation  Total number of moles  =1−α+α+α=(1+α)  px​=(1+α1−α​)p1​  pY​=(1+αα​)p1​  pZ​=(1−α)α​p1​  Kp1​​=[pX​][pY​][pZ​]​=(1+α1−α​)p1​(1+αα​)p1​×(1+αα​)p1​​  =(1+α1−α​)(1+αα​)2p1​​  For equation,Initial molesAt equil.​A1(1−α)​⇔​2B02α​  Total number of moles at equilibrium =(1+α)  pB​=(1+α2α​)p2​  pA​=(α1−α​)p2​  Kp2​​=[pA​][pB​]2​=(1+α1−α​)p2​[(1+α2α​)p2​]2​  Kp2​​=(1+α1−α​)(1+α2α​)2p2​​ ....(ii)  Eq. (i) divide by Eq. (ii)  Kp2​​Kp1​​​=4α2×p2​α2×p1​​  19​=4p2​p1​​  p2​p1​​=136​=36:1

Question Text	The values of $K_{p_{1}}$ and $K_{p_{2}}$ for the reactions $X \Leftrightarrow Y + Z$ ….(i) and $A \Leftrightarrow 2 B$ …(ii) are in ratio of 9 : 1. If degree of dissociation of X and A be equal, then total presure at equilibrium (i) and (ii) are in the ratio.
Answer Type	Text solution:1
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The values of $K_{p_{1}}$ and $K_{p_{2}}$ for the reactions
$X \Leftrightarrow Y + Z$ ….(i)
and $A \Leftrightarrow 2 B$ …(ii)
are in ratio of 9 : 1. If degree of dissociation of X and A be equal, then total presure at equilibrium (i) and (ii) are in the ratio.

Text solutionVerified

Practice questions from similar books

The values of Kp1​​ and Kp2​​ for the reactions X⇔Y+Z ….(i) and A⇔2B …(ii) are in ratio of 9 : 1. If degree of dissociation of X and A be equal, then total presure at equilibrium (i) and (ii) are in the ratio.

Text solutionVerified

Practice questions from similar books

The values of $K_{p_{1}}$ and $K_{p_{2}}$ for the reactions
$X \Leftrightarrow Y + Z$ ….(i)
and $A \Leftrightarrow 2 B$ …(ii)
are in ratio of 9 : 1. If degree of dissociation of X and A be equal, then total presure at equilibrium (i) and (ii) are in the ratio.