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How many times solution of sodium Acetate be diluted at to double the degree of hydrolysis?
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The degree of hydrolysis for salt is given as:
Where is the equilibrium constant for the hydrolysis reaction
' ' is the degree of hydrolysis of the reaction
' ' is the concentration of the solution.
Let consider the concentration of sodium acetate as then the equilibrium constant for the sodium acetate is written as:
Here, and consider ' ' as the degree of hydrolysis. Then, we have
..........(1).
When the degree of hydrolysis is doubled, the concentration would be,
..........(2).
Divide the equation (1) by equation (2). We get
The concentration of solution when we double the degree of hydrolysis is equal to 0.05 M
Thus, the volume of the 0.2 M sodium acetate solution should be four times the initial volume so that the degree of hydrolysis would be double than the initial degree of hydrolysis.
Where is the equilibrium constant for the hydrolysis reaction
' ' is the degree of hydrolysis of the reaction
' ' is the concentration of the solution.
Let consider the concentration of sodium acetate as then the equilibrium constant for the sodium acetate is written as:
Here, and consider ' ' as the degree of hydrolysis. Then, we have
..........(1).
When the degree of hydrolysis is doubled, the concentration would be,
..........(2).
Divide the equation (1) by equation (2). We get
The concentration of solution when we double the degree of hydrolysis is equal to 0.05 M
Thus, the volume of the 0.2 M sodium acetate solution should be four times the initial volume so that the degree of hydrolysis would be double than the initial degree of hydrolysis.
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Question Text | How many times solution of sodium Acetate be diluted at to double the degree of hydrolysis? |
Topic | Equilibrium |
Subject | Chemistry |
Class | Class 11 |
Answer Type | Text solution:1 |
Upvotes | 104 |